The 35-year-old shotstopper joins the Italian club on a free transfer.
The Uruguayan enjoyed previous spells in La Liga with Malaga and Deportivo La Coruna.
Munua earned 21 caps for his country before retiring from international football in 2004.
Restore Data
| Team | P | W | D | L | F | A | GD | PTS | |
| C | AC Milan | 38 | 26 | 8 | 4 | 69 | 31 | 38 | 86 |
| 2 | Inter Milan | 38 | 25 | 9 | 4 | 84 | 32 | 52 | 84 |
| 3 | Napoli | 38 | 24 | 7 | 7 | 74 | 31 | 43 | 79 |
| 4 | Juventus | 38 | 20 | 10 | 8 | 57 | 37 | 20 | 70 |
| 5 | Lazio | 38 | 18 | 10 | 10 | 77 | 58 | 19 | 64 |
| 6 | Roma | 38 | 18 | 9 | 11 | 59 | 43 | 16 | 63 |
| 7 | Fiorentina | 38 | 19 | 5 | 14 | 59 | 51 | 8 | 62 |
| 8 | Atalanta BCAtalanta | 38 | 16 | 11 | 11 | 65 | 48 | 17 | 59 |
| 9 | Hellas VeronaHellas Verona | 38 | 14 | 11 | 13 | 65 | 59 | 6 | 53 |
| 10 | Torino | 38 | 13 | 11 | 14 | 46 | 41 | 5 | 50 |
| 11 | SassuoloSassuolo | 38 | 13 | 11 | 14 | 64 | 66 | -2 | 50 |
| 12 | Udinese | 38 | 11 | 14 | 13 | 61 | 58 | 3 | 47 |
| 13 | Bologna | 38 | 12 | 10 | 16 | 44 | 55 | -11 | 46 |
| 14 | Empoli | 38 | 10 | 11 | 17 | 50 | 70 | -20 | 41 |
| 15 | Sampdoria | 38 | 10 | 6 | 22 | 46 | 63 | -17 | 36 |
| 16 | SpeziaSpezia | 38 | 10 | 6 | 22 | 41 | 71 | -30 | 36 |
| 17 | Salernitana | 38 | 7 | 10 | 21 | 33 | 78 | -45 | 31 |
| R | CagliariCagliari | 38 | 6 | 12 | 20 | 34 | 68 | -34 | 30 |
| R | Genoa | 38 | 4 | 16 | 18 | 27 | 60 | -33 | 28 |
| R | VeneziaVenezia | 38 | 6 | 9 | 23 | 34 | 69 | -35 | 27 |
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